Electrooxidation and Determination of Dopamine Using a Nafion®-Cobalt Hexacyanoferrate Film Modified Electrode
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چکیده
منابع مشابه
Electrooxidation and Determination of Dopamine Using a Nafion®-Cobalt Hexacyanoferrate Film Modified Electrode
The electrocatalysis of dopamine has been studied using a cobalt hexacyanoferrate film (CoHCFe)-modified glassy carbon electrode. Using a rotating disk CoHCFe-modified electrode, the reaction rate constant for dopamine was found to be 3.5 × 105 cm³ mol-1 s-1 at a concentration of 5.0 × 10-5 mol L-1. When a Nafion® film is applied to the CoHCFe-modified electrode surface a high selectivity for t...
متن کاملdetermination of olanzapine and thiourea using electrodes modified by dna and film of copper-cobalt hexacyanoferrate & investigation of electro-oxidation of some catechol derivatives in the presence of 4-phenylsemicarbazid
چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...
15 صفحه اولElectrochemical Sensor for Tryptophan Determination Based on Copper-cobalt Hexacyanoferrate Film Modified Graphite Electrode
In this work, the development of a tryptophan sensor and its application to milkare described. The mixed metal (copper and cobalt) hexacynoferrates are electrodepositedon the graphite electrode, and this film exhibits an electrocatalytic activity towards for theoxidation of tryptophan. The experimental conditions, including the scan cycles, the ratio ofcopper(II) and cobalt(II), pH value, appli...
متن کاملELECTROCHEMICAL BEHAVIOR OF GC, Pt AND Au ELECTRODES MODIFIED WITH THIN FILM OF COBALT HEXACYANOFERRATE
0A thin film of cobalt hexacyanoferrate (CoHCF), an analogue of mixed-valence Prussian blue, was deposited electrochemically on the glassy carbon, platinum and gold electrode surfaces in 0.5M KC1 solution. The electrochemical behavior of these modified electrodes show three couples of redox peaks by CV in a supporting electrolyte solution of 0.5M NaCl, whereas for Au modified electrode only ...
متن کاملSimultaneous determination of dopamine and uric acid using a glassy carbon paste electrode modified with copper- para red complex
A simple approach based on cyclic voltammetry (CV) was developed for the simultaneous determination of dopamine (DA) and uric acid (UA) in the presence of ascorbic acid (AA) using a modified glassy carbon paste electrode (GCPE). In the present study, analytical parameters were optimized and electrochemical performance of modified electrode was investigated. The calibration curves were obtained ...
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ژورنال
عنوان ژورنال: Sensors
سال: 2008
ISSN: 1424-8220
DOI: 10.3390/s8031950